GOTO-ONO Research Group
Department of chemistry
Tokyo Institute of Technology
Recent Publications
Gallery
Original Papers and Reviews
2023
• K. Goto, R. Kimura, R. Masuda, T. Karasaki, S. Sase
“Demonstration of the Formation of a Selenocysteine Selenenic Acid through Hydrolysis of a Selenocysteine Selenenyl Iodide Utilizing a Protective Molecular Cradle”
(Invited paper)
• R. Masuda, T. Karasaki, S. Sase, S. Kuwano, K. Goto
(Hot Paper) (Inside Cover)
• R. Masuda, S. Kuwano, K. Goto
“Modeling Selenoprotein Se-Nitrosation: Synthesis of a Se-Nitrososelenocysteine with Persistent Stability”
(JACS Spotlights) (Supplementary Cover)
• K. Ono, K. Sawanaga, S. Onodera, H. Kawai, K. Goto
“Structural Interconversion Based on Intramolecular Boroxine Formation”
Chem. Eur. J. 2023, 29, e202300995.
(Hot Paper) (Inside Cover)
• K. Goto, T. Sano, R. Masuda, S. Otaka, R. Kimura, S. Sase, and S. Kuwano
"Stable Cysteine Sulfenic Acid: Synthesis by Direct Oxidation of a Thiol, Crystallographic Analysis, and Elucidation of Reactivities"
Phosphorus, Sulfur, Silicon, Relat. Elem., 198, 466–470, (2023). DOI: 10.1080/10426507.2023.2195650
• S. Kuwano, E. Takahashi, J. Kikushima, S. Sase, and K. Goto
"Efficient Oxyselenation and Aminoselenation Utilizing a Selenenyl Iodide Based on the Characteristic Thermodynamics of Its Reaction with Olefins"
New J. Chem., 47, 9569–9574, (2023). DOI: 10.1039/D2NJ06346H
2022
• R. Masuda, S. Kuwano, S. Sase, M. Bortoli, A. Madabeni, L. Orian, and K. Goto
"Model Study on the Catalytic Cycle of Glutathione Peroxidase Utilizing Selenocysteine-Containing Tripeptides: Elucidation of the Protective Bypass Mechanism Involving Selenocysteine Selenenic Acids"
(BCSJ Award), (Front Cover)
• 鍬野 哲, 後藤 敬
"システインスルフェン酸を捕まえる -化学プローブを用いた高反応性化学種の検出"
化学, 77, 70-71 (2022).
• R. Masuda, and K. Goto
"Modeling of selenocysteine-derived reactive intermediates utilizing a nano-sized molecular cavity as a protective cradle"
Methods in Enzymology, 662, 331 (2022).
• S. Kuwano, E. Takahashi, K. Ebisawa, Y. Ishikawa, S. Sase, and K. Goto
"Oxyselenation and aminoselenation of alkenes utilizing an isolable seleneyl iodide"
Mendeleev Commun., 32, 80 (2022).
2021
• A. Shimizu, R. Tobe, R. Aono, M. Inoue, S. Hagita, K. Kiriyama, Y. Toyotake, T. Ogawa, T. Kurihara, K. Goto, N. T. Prakash, and H. Mihara
"Initial Step of Selenite Reduction via Thioredoxin for Bacterial Selenoprotein Biosynthesis"
Int. J. Mol. Sci., 22, 10965 (2021).
• R. Masuda, S. Kuwano, and K. Goto
"Late-Stage Functionalization of the Periphery of Oligophenylene Dendrimers with Various Arene Units via Fourfold C-H Borylation"
(Cover)
• R. Masuda, R. Kimura, T. Karasaki, S. Sase, and K. Goto
"Modeling the Catalytic Cycle of Glutathione Peroxidase by Nuclear Magnetic Resonance Spectroscopic Analysis of Selenocysteine Selenic Acids"
• T. Sano, R. Masuda, S. Sase, and K. Goto
"Isolable small-molecule cysteine sulfenic acid"
(Hot article), (Front Cover), (Chemical Commnications Blog)
2019
"Model study on trapping of protein selenenic acids by utilizing a stable synthetic congener"
(Front Cover)
• S. Sase, R. Kimura, R. Masuda, and K. Goto
New J. Chem., 43, 6830 (2019).
"Modeling of Biologically Relevant Chemical Transformations Involving Thionitrates"
• S. Sase and K. Goto
Phosphorus, Sulfur, Silicon, Relat. Elem., 194, 771 (2019).
• G. N. George, I. J. Pickering, J. J. H. Cotelesage, L. I. Vogt, N. V. Dolgova, N. Regneir, D. Sokaras, T. Kroll, E. Y. Sneeden, M. J. Hackett, K. Goto, and E. Block
Phosphorus, Sulfur, Silicon, Relat. Elem., 194, 618 (2019).
"Visualizing Sulfur with X-rays: From Molecules to Tissues"
2018
• E. Block, B. Dethier, B. Bechand, J. J.H. Cotelesage, G. N. George, K. Goto, E. M. Rengifo, I. J. Pickering, R. Sheridan, E. Sneeden, and L. Vogt
"Ajothiolanes: 3,4-Dimethylthiolane Natural Products from Garlic (Allium sativum)"
J. Agric. Food Chem., 66, 10193 (2018) .
• T. Sano, K. Shimada, Y. Aoki, T. Kawashima, S. Sase, and K. Goto
2017
"Modeling of the Bioactivation of an Organic Nitrate by a Thiol to Form a Thionitrate Intermediate"
Molecules, 22, 19 (2017) .
• K. Goto
"The Concept of Preorganization"
In Comprehensive Supramolecular Chemistry II, J. L. Atwood (ed.) vol 1, pp61-71 (2017).
• E. Sneeden, M. Hackett, J. Cotelesage, R. Prince, M. Barney, K. Goto, E. Block, I. Pickering, and G. George
"Photochemically-Generated Thiyl Free Radicals Observed by X-ray Absorption Spectroscopy"
J. Am. Chem. Soc., 139, 11519-11526 (2017).
2015
• S. Sase, R. Kakimoto, and K. Goto
"Synthesis of a Stable Selenoaldehyde (RCH=Se) by Self-Catalyzed Thermal Dehydration of a Primary-Alkyl-Substituted Selenenic Acid (RCH2SeOH)"
Angew. Chem., Int. Ed., 54, 901-904 (2015).
(Inside Cover)
• S. Sase, M. Hashimoto, and K. Goto
"Oxygen-Atom-Transfer Reactions of a Pd(II) Peroxocarbonate Complex"
Chem. Lett., 44, 157-159 (2015).
• M. Ishihara, N. Abe, S. Sase, and K. Goto
"Synthesis, Structure, and Reactivities of a Stable Primary-Alkyl-Substituted Sulfenic Acid"
Chem. Lett., 44, 615-617 (2015).
• S. Paria, T. Ohta, U. Morimoto, T. Ogura, H. Sugimoto, N. Fujieda, K. Goto, T. Suzuki, and S. Itoh
"Generation, Characterization, and Reactivity of a CuII-alkylperoxide/anilino-radical Complex: Insight into the O-O Bond Cleavage Mechanism"
J. Am. Chem. Soc., 137, 10870-10873 (2015).
• S. Sase, R. Kakimoto, R. Kimura, and K. Goto
"Synthesis of a Stable Primary-Alkyl-Substituted Selenenyl Iodide and Its Hydrolytic Conversion to the Corresponding Selenenic Acid"
Molecules, 20, 21415-21420 (2015).
2014
• Y. Domoto, S. Sase, and K. Goto
"Efficient End-Capping Synthesis of Neutral Donor-Acceptor [2]Rotaxanes under Additive-Free and Mild Conditions"
Chem. - Eur. J., 20, 15998-16005 (2014).
• S. Sase, Y. Ikehara, and K. Goto
"Chloro-(η6-p-cymene)-{3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2"6"-tetramethyl-1,1':3',1"-terphenyl-5'-yl)imidazol-2-ylidene}-ruthenium(II) benzene disolvate"
Acta Crystallogr., Sect. E, 70, m394 (2014).
• K. Goto
"Synergy of Reactivity and Stability in Nanoscale Molecular Architectures"
"Modeling the Catalytic Cycle of Glutathione Peroxidase by Nuclear Magnetic Resonance Spectroscopic Analysis Selenocysteine Selenic Acids"
2013
• K. Goto, S. Yoshikawa, T. Ideue, and S. Sase
"Transnitrosation from a stable thionitrate to an amine with concomitant formation of a sulfenic acid"
J. Sulfur Chem., 34, 705-710 (2013).
2012
• S. Sase, K. Ebisawa, and K. Goto
"Iodide-Promoted Deselenylation of β-Chloro- and β-Oxyselenides to Form Alkenes and Selenenyl Iodides"
Chem. Lett., 41, 766-768 (2012).
• Y. Kobayashi, K. Ohkubo, T. Nomura, M. Kubo, N. Fujieda, H. Sugimoto, S. Fukuzumi, K. Goto, T. Ogura, and S. Itoh
"Copper(I)-Dioxygen Reactivity in a Sterically Demanding Tripodal Tetradentate tren Ligand: Formation and Reactivity of a Mononuclear Copper(II) End-On Superoxo Complex"
Eur. J. Inorg. Chem., 2012, 4574.
2011
• E. Mieda, T. Sasamori, S. Sase, K. Goto, and N. Tokitoh
"Formation of a Unique Fluorosilene-KF Complex Bearing Bulky Substituents"
Chem. Lett., 40, 196-197 (2011).
• S. Sase, Y. Aoki, N. Abe, and K. Goto
"Syntheses of Biologically-relevant Reactive Sulfur Species by Utilizing a Primary Alkyl Steric Protection Group"
Phosphorus, Sulfur Silicon Relat. Elem., 186, 1255-1258 (2011).
• 後藤 敬
"分子キャビティを活用した含ヨウ素高反応性中間体の安定化"
SIS Lett., 12, 2-11 (2011).
• 後藤 敬
"分子のボウルを使って生体反応活性種をモデル化する"
化学と教育, 59, 604-605 (2011).
2010
• K. Goto, D. Sonoda, K. Shimada, S. Sase, and T. Kawashima
"Modeling of the 5'-Deiodination of Thyroxine by Iodothyronine Deiodinase: Chemical Corroboration of a Selenenyl Iodide Intermediate"
Angew. Chem., Int. Ed., 49, 545-547 (2010).
• K. Goto, A. Fukushima, and T. Kawashima
"5,6,7,12-Tetrahydro-6-(1-methylethyl)-12-phenyldibenz[c,f][1,5]azasilocine"
Acta Crystallogr., Sect. E, 66, o20 (2010).
(cover illustration)
• K. Suwa, J. Otsuki, and K. Goto
"Photo- and Thermal Isomerization of Shuttlecock- and Bowl-Equipped Phenylazopyridines"
J. Phys. Chem. A, 114, 884-890 (2010).
• Y. Domoto, K. Saruhashi, A. Fukushima, S. Sase, K. Goto, and T. Kawashima
"Synthesis and Properties of Pentacoordinated Phenoxysilane and Carboxysilanes with Intramolecular Nitrogen-Silicon Coordination"
Phosphorus, Sulfur Silicon Relat. Elem., 185, 1221-1229 (2010).
• Y. Domoto, A. Fukushima, Y. Kasuga, S. Sase, K. Goto, and T. Kawashima
"Catalyst-free Syntheses of [2]Rotaxanes Utilizing a Pentacoordinated Hydrosilane as an End-capping Agent"
Org. Lett., 12, 2586-2589 (2010).
